Acrylic ester copolymer plastisol composition

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

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524296, 524298, 524315, 525902, 523201, C08K 512, C08K 511

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active

052985423

ABSTRACT:
An acrylic ester copolymer plastisol composition comprises (A) copolymer particles comprising, as the major components thereof, (a) 98 to 50 weight % of an alkyl acrylate unit having an alkyl group of 1 to 8 carbon atoms and/or an alkyl methacrylate unit having an alkyl group of 1 to 8 carbon atoms and (b) 2 to 50 weight % of a diene monomer unit, (B) a plasticizer and, optionally, (C) a vulcanizing agent. Another acrylic ester copolymer plastisol composition comprises (A) copolymer particles comprising an ionic crosslinked copolymer prepared by ionic crosslinking of a copolymer comprising, as the major components thereof, (a) 97 to 50 weight % of an alkyl acrylate unit having an alkyl group of 1 to 8 carbon atoms and/or an alkyl methacrylate unit having an alkyl group of 1 to 8 carbon atoms, (b) 2 to 40 weight % of a diene monomer unit and (c) 1 to 20 weight % of a radical polymerizable unsaturated carboxylic acid unit of 3 to 8 carbon atoms having a carboxyl group and (B) a plasticizer. The ionic crosslinking is made through the carboxyl group in the copolymer by addition of a monovalent or divalent metal cation. The acrylic ester copolymer plastisol composition has excellent storage stability even when generally used inexpensive plasticizers are used, gives a molded sheet showing no bleeding and generates no toxic gas on heating to a high temperature, on burning or in case of fire.

REFERENCES:
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patent: 4957955 (1990-09-01), Saur et al.
Derwent Publications Ltd., Abstract No.: 779558/43.
Derwent Publications Ltd., Abstract No.: 88-114473/17.
Derwent Publications Ltd., Abstract No.: 92-387827.

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