Acrylate-styrene-acrylonitrile composition and method of making

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260884, 260885, 260886, C08L 2512, C08L 2906, C08L 3102, C08L 3320

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039446310

ABSTRACT:
An impact-resistant and weatherable thermoplastic composition comprising from about 10 to about 50 weight percent of a crosslinked acrylate elastomer having a Tg of less than 25.degree.C., from about 5 to about 35 weight percent of a crosslinked styrene-acrylonitrile copolymer and from about 15 to about 85 weight percent of a non-crosslinked or linear styrene-acrylonitrile copolymer. The composition is made by a three-step sequence comprising emulsion polymerizing of an alkyl acrylate containing at least one crosslinking monomer, emulsion polymerizing a monomer mixture of styrene, acrylonitrile and at least one crosslinking monomer in the presence of the crosslinked acrylate elastomer formed in the previous step, or a reverse sequence of the prior two emulsion polymerization procedures, and, finally, emulsion or suspension polymerizing of styrene, acrylonitrile in the presence of the previously formed product.

REFERENCES:
patent: 3041307 (1962-06-01), Baer
patent: 3655826 (1972-04-01), Fellmann et al.

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