Acrylate ester monomer production

Details Acrylate ester monomer production Acrylate ester monomer production

1978-11-24

1981-03-24

Trousof, Natalie

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

C07C 6952

Patent

active

042582040

ABSTRACT:
Acrylate ester monomers are produced in high yield and without polymerization by reacting an .alpha.,.beta.-unsaturated organic acid halide and a hydroxyl containing organic compound in the presence of molecular sieves. In the absence of molecular sieves the same reactants produce the monomer ester products in low yield and/or form polymers.

REFERENCES:
patent: 3106593 (1963-10-01), Benesi et al.
Kirk--Othmer, "Encyclopedia of Chemical Technology", 2nd Ed. vol. 13, p. 344.
Ibid. vol. 8, pp. 337-338.
Krasnyl, E. B. et al., "Adsorption of Hydrogen Chlorides on Synthetic Zeolites.", Zh. Prikl. Khim. 1970, 43(11), 2449-2453, (See Chemical Abstracts, vol. 74, 1971, #68,083n.)
Chemical Abstracts, 9th Coll Index. p. 27, 228CS.

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