Acrylate ester ether derivatives

Details Acrylate ester ether derivatives Acrylate ester ether derivatives

1987-08-18

1989-12-26

Killos, Paul J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

562583, 558441, 558462, 568415, 564201, C07C 6973

Patent

active

048899488

ABSTRACT:
A process for synthesizing ethers of alkyl alpha(hydroxymethyl)-acrylate by reacting alkyl acrylate and formaldehyde in the presence of a DABCO catalyst. The ethers may be used as cross-linking agents for thermoplastic polymers. Further, these ethers in turn enable synthesis of cyclopolymers that may show promising biological activity.

REFERENCES:
patent: 3066165 (1962-11-01), Rosenthal et al.
patent: 3288883 (1966-11-01), Teiman et al.
patent: 3743669 (1973-07-01), Hillman et al.
Drewes, L. et al., Synth. Commun. 17(3) 291-29 8, 1987.
Amri et al., Hydroxyalkylation de la Methylvinylcetone et De L'Acrylonitrile en Presence de Diaza-1, 4 Bicyclo[2.2.2]Octane, 27 Tetrahedron Letters, pp. 4307-4308 (1986).
Villieras et al, Wittig-Horner Reaction in Heterogeneous Media: 1, An Easy Synthesis of Ethyl .alpha.-Hydroxymethylacrylate and Ethyl .alpha.-Halomethylacrylates Using Formaldehyde in Water, Synthesis pp. 924-926 (1982).
D. Breslow, "A Polymer That Fights Cancer", Chemtech, pp. 302-307 (1985).

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