Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1989-12-22
1991-03-12
Killos, Paul J.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
526318, 5263182, 526322, 5263231, 526304, 526312, 526316, 526266, 526270, C08F 2004
Patent
active
049994107
ABSTRACT:
A process for synthesizing ethers of alkyl alpha-(hydroxymethyl)-acrylate by reacting alkyl acrylate and formaldehyde in the presence of a DABCO catalyst. The ethers may be used as cross-linking agents for thermoplastic polymers. Further, these ethers in turn enable synthesis of cyclopolymers that may show promising biological activity.
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Villieras et al, Wittig-Horner Reaction in Heterogeneous Media; 1. An Easy Synthesis of Ethyl .alpha.-Hydroxymethylacrylate and Ethyl .alpha.-Halomethylacrylates Using Formaldehyde in Water, Synthesis, pp. 924-926 (1982).
Kusefoglu Selim H.
Mathias Lon J.
Killos Paul J.
University of Southern Mississippi
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