Acid introduction in chlorine dioxide production

Chemistry of inorganic compounds – Halogen or compound thereof – Chlorine dioxide

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C01B 1102

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047803045

ABSTRACT:
Chlorine dioxide is formed by reduction of sodium chlorate in a sulphuric acid-containing reaction medium. Sulphuric acid is introduced to the reaction medium in air atomized form to promote rapid and efficient mixing of the sulphuric acid, thereby avoiding chlorine dioxide decomposition at hot spots resulting from inefficient mixing of acid with the reaction medium.

REFERENCES:
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patent: 2641528 (1953-06-01), Audoynaud
patent: 3816077 (1974-06-01), Fuller et al.
patent: 3895100 (1975-07-01), Cowley
patent: 4105751 (1978-08-01), Caillol
patent: 4203961 (1980-05-01), Cowley
patent: 4251502 (1981-02-01), Forster
patent: 4486399 (1984-12-01), Lobley

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