Acid functional fluoropolymer membranes and method of...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Ion-exchange polymer or process of preparing

Reexamination Certificate

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C525S326200, C525S344000, C525S366000

Reexamination Certificate

active

10984031

ABSTRACT:
Methods are provided to make acid functional fluoropolymers by: a) dehydrofluorinating a starting fluoropolymer with a dehydrofluorinating agent to form an unsaturated fluoropolymer; b) adding an acidifiable nucleophilic functionalizing agent to a double bond of the unsaturated fluoropolymer; and c) acidifying the added acidifiable function. Acid functional fluoropolymers and ion conducting membranes thereof are also provided, including acid functional fluoropolymer having pendent groups according to the formula: —X—Ar—An, wherein X is selected from O, S or NR, where R is selected from H and C1–C30 alkyl or aryl, which are optionally substituted, wherein Ar is a C6–C30 aromatic group, which is optionally substituted, wherein A is an acidic function or salt thereof, wherein a can be independently chosen to be 1, 2 or 3.

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T. Zawodzinski et al., Los Alamos National Laboratory, “Determination of Water Diffusion Coefficients in Perfluorosulfonate Ionomeric Membranes”, Journal of Physical Chemistry, vol. 95, No. 15, Jul. 25, 1991, pp. 6040-6044.
LaCont et al., “Solid Polymer Electrolyte Electrochemical Cells: Electrode and Other Materials Considerations”, The Electrochemical Society Proceedings, vol. 77-6, 1977, pp. 354-374.

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