Acid-catalyzed hydrolysis of organic hydroperoxide employing a p

Details Acid-catalyzed hydrolysis of organic hydroperoxide employing a p Acid-catalyzed hydrolysis of organic hydroperoxide employing a p

1976-11-08

1979-04-03

Morgenstern, Norman

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260464, 260465F, 260465G, 260465H, 2604656, 2604657, 2604658R, 260586M, 260590R, 260590D, 260591, 260592, 260593A, 260598, 260599, 260601R, 260601H, 260606, 568569, 568650, 568741, 568744, 568747, 568765, 568768, 568774, 568780, 568798, C07C 3708, C07C 4500

Patent

active

041477260

ABSTRACT:
An organic hydroperoxide is hydrolyzed by acid-catalysis in a reaction medium comprising essentially a mixture of a polar solvent, e.g. a low boiling, low molecular weight alcohol and/or sulfolane and phenol. Specifically cyclohexanone and phenol are obtained from cyclohexylbenzene hydroperoxide.

REFERENCES:
patent: 2430865 (1947-11-01), Farkas et al.
patent: 2663735 (1953-12-01), Filar et al.
patent: 2728796 (1955-12-01), Vandenberg
patent: 2734085 (1956-02-01), Adams et al.
patent: 3948995 (1976-04-01), Jouffret
patent: 3978141 (1976-08-01), Jouffret
patent: 4021490 (1977-05-01), Hudson

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