Acetylenic alcohols and ethers as accelerators for hydrosilation

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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C07F 708

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active

054498023

ABSTRACT:
A hydrosilation process where a silicon hydride is reacted with an unsaturated reactant in the presence of a platinum catalyst and an accelerator selected from a group consisting of acetylenic alcohols, silated acetylenic alcohols, and acetylenic ethers. The accelerators are especially useful for the hydrosilation of unsaturated reactants where the unsaturation is in the internal portion of the reactant's structure, for example, as in cyclopentene and cyclohexene. The unsaturated ketone accelerators are effective in the presence or absence of oxygen.

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patent: 5191103 (1993-03-01), Mehta et al.
patent: 5359111 (1994-10-01), Kleyer et al.

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