Acetophenone recovery and purification

Distillation: processes – separatory – With chemical reaction – Including step of adding catalyst or reacting material

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203 17, 203 44, 203 45, 203 73, 203 80, 568335, 568749, B01D 310

Patent

active

045591105

ABSTRACT:
Distillation of the heavy waste stream from the manufacture of phenol via the cumene process provides an overhead stream containing phenol, acetophenone and 2-phenyl propionaldehyde. Extraction of the overhead stream with aqueous caustic removes the phenol and subsequent distillation of the remaining two components in the presence of a catalytic amount of caustic provides a substantially pure acetophenone distillate.

REFERENCES:
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patent: 2727074 (1955-12-01), Bewley
patent: 2824048 (1958-02-01), Hupe et al.
patent: 2992169 (1961-07-01), Gregory et al.
patent: 3668256 (1972-06-01), Brundege
patent: 4169109 (1979-09-01), Yoshida et al.
patent: 4283568 (1981-08-01), Pujado
patent: 4298765 (1981-11-01), Cochran et al.

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