Acetal hydrazones of 2-hydrazino-3H-1,4-benzodiazepine

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260296B, 2602948C, 2603407, 260295K, 2603409R, C07D24320, C07D40104, C07D40512, C07D40514

Patent

active

041071590

ABSTRACT:
Compounds of the formula: ##STR1## wherein R.sub.1 is alkyl of 1 to 3 carbon atoms, inclusive; wherein R.sub.2 is hydrogen, methyl or ethyl; wherein R.sub.3 is hydrogen, fluoro, chloro, bromo, nitro and --CF.sub.3 ; and wherein A is phenyl, o-chlorophenyl, o-fluorophenyl, 2,6-difluorophenyl, and 2-pyridyl, are prepared by treating a hydrazino compound of the formula: ##STR2## with a carbonyl compound II: ##STR3## wherein R.sub.1 is defined as above, and R', R" are alkyl of 1 to 3 carbon atoms, inclusive or the group ##STR4## is a cyclic acetal to give a compound of formula III: ##STR5## wherein R.sub.1, R.sub.2, R.sub.3, R', R" and Ar are defined as above, and cyclizing compound III to give the compound IV above.
Compounds III and IV, including the pharmacologically acceptable acid addition salt of these compounds, have sedative, anxiolytic and muscle-relaxing activity and can be used for the treatment of anxieties or muscle strains of mammals, including man.

REFERENCES:
patent: 3864328 (1975-02-01), Fryer et al.
patent: 3946032 (1976-03-01), Allgeier et al.

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