Acetal copolymers with backbone double bonds and graft copolymer

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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Details

524 83, 524542, 528249, C08F28306, C08G 224

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active

049007831

ABSTRACT:
Acetal copolymers of trioxane and 1,3-dioxep-5-ene having a high degree of crystallinity and specific mole percent incorporations of 1,3-dioxep-5-ene are synthesized.
The invention also provides a process for producing highly crystalline acetal copolymers by copolymerizing triozane and 1,3-dioxep-5-ene and precipitating the copolymer product from solution.
The copolymers show much improved stability against halogen degradation.

REFERENCES:
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patent: 3337587 (1967-08-01), Tinsley, Jr., et al.
R. C. Schulz, Makromol. Chem. Suppl. 13, 123-136 (1985).
W. Hellerman and R. C. Schulz, Makromol. Chem., Rapid Commun. 2, 585-589 (1981).
P. H. Plesch and P. H. Westermann, Polymer, 10:105 (1965).
E. J. Vandenberg, J. of Polymer Sci. Polymer Chem. Ed., 23, 951-970 (1985).
S. Penszek, et al, Adv. Polymer Sci. 68/69, Cationic Ring Opening Polymerization, 2. Synthetic Applications p. 91 (1981).

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