Absorber packing and method

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Carbon dioxide or hydrogen sulfide component

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423230, 4235731, 4235762, C01B 1716, C01B 3120

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active

049991728

ABSTRACT:
A method and arrangement for facilitating removal of hydrogen sulfide from a combuation process gas includes provision of a packed bed scrubber having packing material therein comprising a polymeric substance having an outer surface with a substantially hydrophilic character. For preferred arrangements and methods, the packing material comprises a polymeric substance having a plurality of sulfonic acid groups, or neutralized sulfonic acid groups, thereon. A method of providing such packing material comprises reaction of a substantially hydrophobic packing material with sulfur trioxide. Preferred scrubber arrangements utilizing segmented packing beds are also disclosed. The result of the described methods and processes is a scrubber arrangement having a substantially reduced propensity for plugging, by comparison to conventional scrubber arrangements, when utilized for otherwise conventional scrubbing processes.

REFERENCES:
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patent: 4537752 (1985-08-01), Weber
patent: 4541998 (1985-09-01), Weber
Bailar et al., University Chemistry, Boston, Massachusetts, 427 (1965).
Linek et al., Vt. Verfahrenstechnik, 17, 382 (1983).
Linek et al., Chem. Eng. Res. Des., 62, 13 (1984).
Linek et al., Chem. Eng. Sci., 29, 1955 (1974).
Linek et al., "Scientific Papers of the Prague Institute of Chemical Technology", K 19, 189 (1984).
Strigle, R., "Random Packing and Packed Towers: Design and Applications", Gulf Publishing Co., Houston, Texas, pp. 46-54.

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