Abrasion resistant UV-curable hardcoat compositions

Coating processes – Direct application of electrical – magnetic – wave – or... – Polymerization of coating utilizing direct application of...

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427519, 522 37, 522 83, 522 84, 522 99, 428412, 428447, 524806, 526279, 528 26, 528 32, B05D 306, C08F 250, C08K 334, B32B 904

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052427196

ABSTRACT:
A method of making a UV curable hardcoat composition uses a strip-free process and produces hardcoats having good scribed tape-pull adhesion, high resistance to scratching and a low delta taber haze after abrading for 500 cycles with a 500 gram weight. UV curable hardcoat compositions are also provided which contain high solids contents and high mole percentages of photoinitiator. Compositions containing methoxypropanol as a water miscible alcohol and methylbenzoylformate as a photoinitiator exhibit high taber hardness and can be made by processes which obviate the need for a time and energy consuming solvent-strip step. The processes are not only shorter, but safer than processes which include a solvent-strip step.

REFERENCES:
patent: 4455205 (1984-06-01), Olson et al.
patent: 4486504 (1984-12-01), Chung
patent: 4491508 (1985-01-01), Olson et al.
patent: 4576870 (1986-03-01), Liebler et al.
patent: 4650845 (1987-03-01), Hegel

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