7.beta.-Arylalkyl-3-methoxy or 3-hydroxy-4,5.alpha.-epoxy-6.beta

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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424260, 546 39, 546 45, C07D48902, A61K 31485

Patent

active

044409311

ABSTRACT:
Disclosed are 7.beta.-alkyl or arylalkyl-3-methoxy or hydroxy-4,5.alpha.-epoxy-6.beta.-hydroxy-7.alpha.-hydroxymethyl-17-methyl or cycloalkylmethylmorphinans of the formula: ##STR1## In the above formula, R is H or methyl, R.sub.1 is methyl, cyclopropylmethyl or cyclobutylmethyl, n is 2 to 4 and Y is H or phenyl. These compounds are useful as narcotic analgesics.

REFERENCES:
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patent: 4347361 (1982-08-01), Quick et al.
Kotick, et al., J. Med. Chem., 24(12), pp. 1445-1450, (1981).
Bentley, et al., J. Am. Chem. Soc., 89(13), pp. 3267-3273, (1967).
Stork, "The Alkaloids", vol. VI, Manske, ed., Academic Press, New York, (1960), p. 226.
Quick, et al., J. Med. Chem., 25(8), pp. 983-986, (1982).
Leland, et al., J. Org. Chem., 48(11), pp. 1813-1819, (1983).
Kotick, et al., J. Med. Chem., 26(7), pp. 1050-1056, (1983).

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