6-epithioethyl-3-oxatricyclo [3.2.1.0.sup.2.4 ] octane and proce

Details 6-epithioethyl-3-oxatricyclo [3.2.1.0.sup.2.4 ] octane and proce 6-epithioethyl-3-oxatricyclo [3.2.1.0.sup.2.4 ] octane and proce

1991-04-09

1992-10-06

Hollrah, Glennon H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

549 1545, C07D40904

Patent

active

051533316

ABSTRACT:
6-Epithioethyl-3-oxatricyclo [3.2.1.0.sup.2.4 ] octane, a novel compound, is prepared by reaction of the corresponding 6-epoxyethyl-3-oxatricyclo [3.2.1.0.sup.2.4 ] octane with an ammonium or alkali or alkaline earth metal thiocyanate or a thiourea, and useful as a monomer for preparations of, e.g., heat resistant plastics and plastics for optical use.

REFERENCES:
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patent: 4233131 (1980-11-01), Ratcliffe et al.
M. Sander, Chem. Rev., "Thiiranes," 66, pp. 297-339 (1966).
Chemical Abstracts, vol. 90, 1979, Columbus, Ohio, US; abstract No. 22696s, Kassyan L.: "Synthesis of cyclic diepoxides".
Chemical Abstracts, vol. 95, No. 36, 1981, Columbus, Ohio, US; abstract No. 133908k, Lozinskii M. O.: "Polymeric composition" p. 41: abstract SU-A-836 040 (Dnepropetrovsk State University) May 7, 1981.

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