5H Dibenzo (a,d) cycloheptene, 10,11 dihydro, 5(1-halo-3-dimethy

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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2602471R, 2602475R, 2602477N, 2602477T, 260290R, 260290HL, 260333, 2603265S, 2603265R, 2603265C, 2603265CA, 2603265E, 26029356, 26029358, 2602948B, 2605705CA, 2605705P, 26050118, 424248, 424263, 424274, 424330, C07C 8700, C07C 8729

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active

039911039

ABSTRACT:
11-Halo derivatives of amitriptyline and its analogues, i.e. 5-(1'-halo-3'-aminoprop-1'-yl-idene)-5H-dibenzo[a,d]-10,11-dihydrocyclohep tenes and corresponding 11-oxa analogues as well as the acid addition salts thereof, have notable anti-depressant and tranquillising activity. They are prepared by reacting a 5-(3'-aminoprop-1'-ylidene)-5H-dibenz[a,d]-10,11-dihydrocycloheptene or an 11-oxa analogue thereof, or an acid addition salt thereof, with an electrophilic halogenating agent.

REFERENCES:
patent: 3372196 (1968-03-01), Engelhardt
patent: 3445519 (1969-05-01), Kollonitsch
Barton et al., Chemical Communications, pp. 227-228, (1969).
Barton et al., Chemical Communications, pp. 804-808, (1968).
Tatlow et al., Advances in Fluorine Chemistry, Butterworth & Co., p. 183, (1973).
Weininger, Contemporary Organic Chem., Holt Rinehart & Wilson Inc., pp. 179-183 (1972).

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