5-Unsubstituted-9,9-dimethyl-6,7-benzomorphans

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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424267, C07D22126, C07D40506

Patent

active

042686733

ABSTRACT:
The invention is concerned with certain novel 6,7-benzomorphan derivatives having analgesic and/or morphine-antagonistic properties of the formula ##STR1## wherein each R is a lower alkyl group; R.sub.1 is a hydrogen atom, or an alkyl, haloalkyl, alkenyl, haloalkenyl, alkinyl, cycloalkyl, cycloalkenyl, cycloalkylalkyl, cycloalkenylalkyl, cycloalkylidenealkyl, aralkyl, heteroarylalkyl or heterocycloalkylalkyl group; R.sub.2 is a hydrogen atom or a hydroxy, alkoxy, alkoxyalkoxy or acyloxy group.
Such 6,7-benzomorphans may be in the form of their optically active enantiomers and/or their therapeutically acceptable salts. Methods for producing such 6,7-benzomorphan derivatives, and novel intermediates useful for such production are also disclosed and form part of the invention.

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Oh-Ishi, T., et al., J. Org. Chem., 39(10), 1347-1349 (1974).
Shriner, R. in Organic Reactions, (Adams et al., editors), John Wiley, New York, 1942, vol. 1, p. 2.
Posner, G., in Organic Reactions, (Bittman et al., editors), John Wiley, New York, 1972, vol. 19, pp. 25-32.

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