4-Methyl-4-phenyl-1-pentanals, their preparation and their use a

Perfume compositions – Perfume compositions – Oxygen containing active ingredient

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568425, 568426, A61K 746, C07C 4752

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active

048372013

ABSTRACT:
4-methyl-4-phenyl-1-pentanals of the general formula I ##STR1## where R.sup.1 is hydrogen or C.sub.1 -C.sub.4 -alkyl and R.sup.2 is hydrogen or methyl, with the exception of 4-methyl-4-phenyl-1-pentanal, and the use of the methylphenylpentanals of the formula I for imparting fragrance properties to, or improving or modifying the fragrance properties of, perfumes and perfumed products, and the preparation of these compounds by hydroformylation of the corresponding 3-methyl-3-phenyl-1-butenes of the general formula II ##STR2## and, if required, subsequent reaction with formaldehyde and partial hydrogenation.

REFERENCES:
patent: 4008276 (1977-02-01), Zenitz
patent: 4486607 (1984-12-01), Webb
patent: 4709109 (1987-11-01), Sperling et al.
Journal of Organic Chemistry, vol. 29, No. 7, pp. 1663-1669, Free-Radical Rearrangements, Jul. 13, 1964.
Arctander, Parfume and Flavor Chemicals, Montclair 1969, 2172 and 2204.
J. Am. Chem. Soc., vol. 65, pp. 1469-1471, Aug. 1943, Formation of Cyclopropanes from Monohalides. Whitmore et al.

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