Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1981-03-23
1983-05-03
Gerstl, Robert
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
560 11, 562429, 562577, C07C14706
Patent
active
043820379
ABSTRACT:
Novel 3-formyl-4-methyl-pentanoic acid derivatives of the formula ##STR1## wherein Y is an aromatic group, R.sub.2 and R.sub.3 are individually alkyl of 1 to 4 carbon atoms or taken together with the carbon atom to which they are attached form a carbon homocycle of 3 to 6 carbon atoms, the Rs are alkyl of 1 to 6 carbon atoms or together form a polymethylene of 2 to 3 carbon atoms and Z' is selected from the group consisting of --COOH and Z and Z is selected from the group consisting of cyano and --COOR.sub.1 wherein R.sub.1 is alkyl of 1 to 6 carbon atoms and their preparation which are useful for the preparation of 3-formyl-4-R.sub.2 R.sub.3 -but-3-ene-1-oic acid which is an intermediate for the preparation of a compound of the formula ##STR2## wherein R.sub.4 is hydrogen or the remainder of an alcohol of the formula R.sub.1 OH by the process of copending, commonly assigned U.S. patent application No. 153,338 filed May 27, 1980.
REFERENCES:
patent: Re27592 (1973-03-01), Martel et al.
House, Modern Synthetic Reaction, p. 494 (1972).
Demoute Jean-Pierre
Martel Jacques
Tessier Jean
Gerstl Robert
Roussel Uclaf
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