3-(ether and thioether)-3-(indolyl)-phthalides

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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C07D40504

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active

046616055

ABSTRACT:
This invention relates to 3-aryl or heteroaryl-3-alkoxy, phenoxy-, alkylthio- or phenylthiophthalides useful as color formers, particularly in carbonless duplicating and thermal marking systems, which are prepared by the interaction of 2-(disubstituted amino)phenylcarbonylbenzoic acids with an acid chloride or an anhydride of an alkanoic acid in the first step and a further reaction of the product of the first step with an alcohol, a thioalcohol, a phenol or a thiophenol in a second step.

REFERENCES:
patent: 3941807 (1976-03-01), Borrov
patent: 4431819 (1984-02-01), Schmidt et al.
M. Newman and C. McCleary, J. Amer. Chem. Soc. 63, 1537-1541 (1941).
M. Newman and C. Courduvelis, J. Org. Chem. 30, 1795-1800 (1965).
M. Newman and C. Courduvelis, J. Amer. Chem. Soc. 88, 781-784 (1966).
M. Newman and L. Lala, Tetrahedron Letters 34, 3267-3269 (1969).
M. Bhatt and K. Kamath, J. Chem. Soc. (B), 1036-1044 (1968).

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