3-Endo-protected hydroxyl-tricyclo[3,2,0,0.sup.2,7 ]heptan-6-one

Details 3-Endo-protected hydroxyl-tricyclo[3,2,0,0.sup.2,7 ]heptan-6-one 3-Endo-protected hydroxyl-tricyclo[3,2,0,0.sup.2,7 ]heptan-6-one

1978-11-01

1983-06-28

Garner, Vivian

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

260389, 260395, 260404, 260408, 260410, 2604105, 549421, 560 8, 560 20, 560 55, 560 66, 560 73, 560 81, 560 84, 560 96, 560100, 560105, 560107, 568315, 568326, 568347, 568373, C07D30912, C07C 69013, C07C 6914, C07C 49517, C07C 49753

Patent

active

043907210

ABSTRACT:
A novel 3-endo-protected hydroxyl-tricyclo[3,2,0,0.sup.2,7 ]heptan-6-one is described which can be alkylated stereospecifically to give a 5-endo-protected hydroxyl-bicyclo[2,2,1]heptan-2-one which may then be converted via a sequence of reactions into prostaglandins of the F-series having a protecting group at the 9-position. The synthesis of the tricyclo[3,2,0,0.sup.2,7 ]heptan-6-one is also described.

REFERENCES:
patent: 3862178 (1975-01-01), Brown et al.
patent: 3992438 (1976-11-01), Corey et al.
patent: 4002691 (1977-01-01), Shepherd, Jr.
Gilbert et al., Tetrahedron Letters, No. 3, pp. 2545-2548, Jul. 1975, Pergamon Press, Great Britain.

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