3-Endo-protected hydroxyl-tricyclo[3,2,0,0.sup.2,7 ]-heptan-6-on

Details 3-Endo-protected hydroxyl-tricyclo[3,2,0,0.sup.2,7 ]-heptan-6-on 3-Endo-protected hydroxyl-tricyclo[3,2,0,0.sup.2,7 ]-heptan-6-on

1976-12-02

1979-01-16

Shaver, Paul F.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2603459P, 26034321, 260586R, 260586F, 2603452, 260590, 260598, 260600R, 560256, 560101, 560107, 560105, 560121, 560 55, 560118, 562503, 562465, 562500, C07F 718

Patent

active

041349113

ABSTRACT:
A novel 3-endo-protected hydroxyl-tricyclo[3,2,0,0.sup.2,7 ]-heptan-6-one is described which can be alkylated stereospecifically to give a 5-endo-protected hydroxyl-bicyclo [2,2,1]heptan-2-one which may then be converted via a sequence of reactions into prostaglandins of the F-series having a protecting group at the 9-position. The synthesis of the tricyclo[3,2,0,0.sup.2,7 ]heptan-6-one is also described.

REFERENCES:
patent: 3997566 (1976-12-01), Morton
patent: 4053485 (1977-10-01), Morton

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