3-Benzyl-3-azabicyclo(3.1.0)hexane-2,4-dione

Details 3-Benzyl-3-azabicyclo(3.1.0)hexane-2,4-dione 3-Benzyl-3-azabicyclo(3.1.0)hexane-2,4-dione

1978-07-06

1980-01-15

Tovar, Jose

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

26032687, C07D20952

Patent

active

041838572

ABSTRACT:
3-Azabicyclo(3.1.0)hexane, a precursor for preparing 3-azabicyclo(3.1.0)hexane-2-carboxylic acid, a plant gametocide, is prepared by (a) treating cis-1,2-cyclopropanedicarboxylic acid with benzylamine, to form 3-(benzyl)-3-azabicyclo(3.1.0)hexane-2,4-dione, (b) selectively reducing the dione to 3-(benzyl)-3-azabicyclo(3.1.0)hexane, and (c) hydrogenolysis of that compound to 3-azabicyclo(3.1.0)hexane.

REFERENCES:
patent: 3418336 (1968-12-01), Grogan et al.
patent: 3654305 (1972-04-01), German
patent: 3745170 (1973-07-01), Fujinam et al.
Leonard M. Rice, J. Org. Chem. vol. 24, 1520-1523 (1959).
Wendish & Naegle, Org. Mag. Res. Spect. 2, 619-624 (1970).

Affiliated with

Also associated with

Rating

3-Benzyl-3-azabicyclo(3.1.0)hexane-2,4-dione does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with 3-Benzyl-3-azabicyclo(3.1.0)hexane-2,4-dione, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and 3-Benzyl-3-azabicyclo(3.1.0)hexane-2,4-dione will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1028056