3-Amino-4-C-carboxy-2,3,4,6-tetradeoxy-D-arabino-hexose trimethy

Details 3-Amino-4-C-carboxy-2,3,4,6-tetradeoxy-D-arabino-hexose trimethy 3-Amino-4-C-carboxy-2,3,4,6-tetradeoxy-D-arabino-hexose trimethy

1981-03-30

1982-04-13

Raymond, Richard

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

549 22, 549 39, 549 89, 562426, 562556, C07C149243, C07D33900, C07D33906, C07D33908

Patent

active

043249000

ABSTRACT:
Disclosed is a chiral, total synthesis of thienamycin from D-glucose, which proceeds via intermediates I, II, and III and joins aldehyde IV or acid V, which are known to be useful in the total synthesis of thienamycin (VI): ##STR1## wherein R.sup.1 is hydrogen or a removable protecting group;

REFERENCES:
patent: 4234596 (1980-11-01), Christensen et al.
Hanessian et al., Absts. Papers, 181st ACS National Meeting, CARB 27 (1981).

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