3-amino-2-hydroxybornane derivatives, asymmetric Michael reactio

Details 3-amino-2-hydroxybornane derivatives, asymmetric Michael reactio 3-amino-2-hydroxybornane derivatives, asymmetric Michael reactio

1990-12-06

1992-09-08

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568347, C07C 4569

Patent

active

051460033

ABSTRACT:
A 3-amino-2-hydroxybornane derivative represented by formula (I): ##STR1## wherein R represents a furfuryl group, a 1-methylpyrrolylmethyl group, or a benzyl group, is disclosed. The compound is useful as a ligand in an asymmetric Michael reaction, particularly for the production of an optically active muscone.

REFERENCES:
Suzuki et al., Chem. Abst., vol. 143062e (1983).
The Chemical Society of Japan, Lectures (II) of the 58th Spring Meeting, Lecture No. 3 IIID 16, p. 1602 (1989).
2nd International Conference of Hetero Atomic Chemistry, Abstracts, p. 129, Lecture No. PA-44 (1989).
Fusai Gosei To Kogaku Bunkatsu No Shinpo, Kagaku Zokan, No. 97, pp. 44-45, Kaguku Dojin (1982).
Mookherjee et al, J. Org. Chem., vol. 36, No. 26, pp. 4124-4125 (1971).

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