3,5-dimethyl-4-methoxypyridine derivatives

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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546301, 546303, C07D21368

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active

050668102

ABSTRACT:
A process for the preparation of compounds of formula I ##STR1## in which X is the radical OH or Cl, by the catalytic hydrogenation of 3,5-dimethyl-4-methoxy-2-cyanopyridine, subsequent reaction of the resulting 3,5-dimethyl-4-methoxy-2-aminomethylpyridine to give 3,5-dimethyl-4-methoxy-2-hydroxymethylpyridine and, if desired, chlorination to give 3,5-dimethyl-4-methoxy-2-chloromethylpyridine, and the novel intermediate 3,5-dimethyl-4-methoxy-2-aminomethylpyridine.

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Hilgetag et al., Ed. "Preparative Organic Chemistry", N.Y.: John Wiley & Sons, 1972, p. 342.
Buelta Casado et al., Chemical Abstracts, vol. 106, 102092f (1987).

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