3,5-Bis(chloromethylthio)-4-cyanoisothiazole

Details 3,5-Bis(chloromethylthio)-4-cyanoisothiazole 3,5-Bis(chloromethylthio)-4-cyanoisothiazole

1978-02-24

1979-03-06

Daus, Donald G.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07D27500

Patent

active

041430433

ABSTRACT:
Novel compounds, i.e. 3,5-bis(chloromethylthio)-4-cyanoisothiazole; 2,5-bis(chloromethylthio)-1,3,4-thiadiazole; and 3,5-bis(chloromethylthio)-1,2,4-thiadiazole are prepared by reacting an alkali metal aryl mercaptide with bromochloromethane in the presence of a quaternary ammonium salt. These novel compounds have microbiological activity and are also useful as intermediates in the preparation of the corresponding thiocyanomethylthio compounds which have antimicrobial activity.

REFERENCES:
patent: 3869466 (1975-03-01), Mixan
Hatchard, W. R., "Journal of Organic Chemistry," 29, pp. 660-668.

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