3,4-Anhydro-2,6-dideoxy-L-ribohexose

Details 3,4-Anhydro-2,6-dideoxy-L-ribohexose 3,4-Anhydro-2,6-dideoxy-L-ribohexose

1979-06-13

1980-12-09

Chan, Nicky

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07D31100

Patent

active

042383994

ABSTRACT:
A process to produce methyl 3,4-anhydro-2,6-dideoxy-L-ribohexopyranoside, its enantiomer and racemate thereof.
The compound is useful as an intermediate in the production of daunosamine which in turn is a prime constituent in the anti-cancer agents Daunomycin and Adriamycin. Also disclosed are novel intermediates in the process.

REFERENCES:
patent: 3997663 (1976-12-01), Pinnert et al.
Shono et al., Tetrahedron Letters, 17, 1363 (1976).
Marsh et al., Chem. Comm., 973 (1967).
Horton et al., Carbohydrate Research, 44, 227 (1975).
Wong et al., Can. J. Chem., 53, 3144 (1975).

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