3-(1,3-Dithian-2-yl)-4-cyclo-pentene-2-carboxylic acids, esters

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260468D, 260468J, 260468L, 260470, 260514D, 260514J, 260514L, 260516, 260544Y, 260557R, 260558S, 260586R, 260586F, 260593R, 260598, 260590C, 260590D, 2605855, C07D33908

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039474690

ABSTRACT:
The invention relates to the stereoisomers of novel cyclopentene derivatives and to the preparation thereof.
The cyclopentene derivatives are obtained by cycloaddition reaction between cyclopentadiene and a mono-or bis-thioalkyl (or aryl) ketene and reaction between the obtained product and a nucleophile agent.
The compounds of the invention are intermediate products valuable for the preparation of different compounds, among which compounds of the prostaglandin type.

REFERENCES:
ghosez et al., Tetrahedron Letters, 1966, pp. 135-139.
J. Chem. Soc. (C), 1971, pp. 1764-1769, Brook et al.
J. Org. Chem. 28 : 1433-1435, (1963), McDonald et al.

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