2-Tolyl-4,5-dihydroxymethyl imidazole

Details 2-Tolyl-4,5-dihydroxymethyl imidazole 2-Tolyl-4,5-dihydroxymethyl imidazole

1977-06-02

1978-10-24

Trousof, Natalie

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C07D23364

Patent

active

041222776

ABSTRACT:
A process for producing C-methylol imidazoles which comprises reacting imidazole compounds containing an aryl group at the 2-position with formaldehyde in a reaction medium having a pH of at least 7 whereby the formaldehyde adds to the carbon atom of the imidazole ring. The products are either monomethylol imidazoles or dimethlol imidazoles depending upon the starting imidazole compounds. Most of the C-methylol imidazoles thus obtained are new compounds.

REFERENCES:
Dziuron et al., I Arch. Pharmaz. 1973, vol. 306, pp. 347-350.
Dziuron et al., II Arch. Pharmaz. 1974, vol. 307, pp. 89-95.
Imbach et al., Bulletin Soc. Chim. (France) 1971, pp. 1052-1060.
Cornforth et al., J. Chem. Soc. 1948, pp. 731-735.
Perez, Chem. Abst. 1953, vol. 47, col. 2764.

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