2-Hydrocarbyl ethers of cycloaliphatic ketones and process for t

Details 2-Hydrocarbyl ethers of cycloaliphatic ketones and process for t 2-Hydrocarbyl ethers of cycloaliphatic ketones and process for t

1973-11-20

1976-01-06

Morgenstern, Norman

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260586M, 260590, 260610R, 260613R, C07C 4500

Patent

active

039313247

ABSTRACT:
Compounds of the formula ##EQU1## WHEREIN R is a hydrocarbyl radical selected from the group consisting of alkyl, aralkyl and cycloalkyl having from 3 to 12 carbon atoms and n is an integer from 1 to 9 are prepared by reacting a 1,1-bis (hydrocarbyl peroxy) cycloalkane with cycloaliphatic ketones in the presence of a molybdenum containing catalyst. The 1,1-bis (hydrocarbyl peroxy) cycloalkane can be prepared in situ from an organic hydroperoxide and a cycloalkanone. The compounds have utility as solvents and certain specific members of the class have utility as intermediates to adipic acid by further oxidation or as an intermediate to 2-t-butoxyphenol by known dehydrogenation methods.

REFERENCES:
patent: 2713068 (1955-07-01), Spezale
patent: 3431308 (1969-03-01), Zimmermann et al.

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