2-Haloadamantyl-(1)-acetamides

Details 2-Haloadamantyl-(1)-acetamides 2-Haloadamantyl-(1)-acetamides

1974-06-26

1976-10-12

Hines, Robert V.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

204158R, 424274, C07C10319

Patent

active

039858030

ABSTRACT:
A process for preparing 2-haloadamantyl-(1)-acetamides of the formula I ##SPC1##
wherein X is chloro, bromo or iodo, in which an N-haloadamantyl-(1)-acetamide of the formula II ##SPC2##
wherein X is as defined above, is subjected to photochemical irradiation.

REFERENCES:
patent: 3218355 (1965-11-01), Paulshock
patent: 3591642 (1971-07-01), Szinai et al.
patent: 3644356 (1972-02-01), Chakrabarti et al.
patent: 3654301 (1972-04-01), Chakrabarti
patent: 3789072 (1974-01-01), Bernstein
Lunn et al., J. Chem. Soc. (C), 1968, pp. 1657-1660.
"Synthesis of Adamantane Derivatives," Sasaki et al., Bull. Chem. Soc. Japan, 1968, 41(1), pp. 238-240.
"Anodic Acetamidation of Adamantane and 1-Haloadamantanes," Koch et al., Tetrahedron Letters No. 9, pp. 693-696 (1973).

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