2-Furyl-(3,4-dimethyl-2-pyridyl)-carbinol

Details 2-Furyl-(3,4-dimethyl-2-pyridyl)-carbinol 2-Furyl-(3,4-dimethyl-2-pyridyl)-carbinol

1978-10-06

1979-11-13

Randolph, John D.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

424263, C07D40502

Patent

active

041744519

ABSTRACT:
Furfural is reacted with 2-bromo-3,4-dimethylpyridine in an ether solution of butyl-lithium at about -15.degree. C. in an inert atmosphere to form 2-furyl-(3,4-dimethyl-2-pyridyl)-carbinol, having analgesic properties.

REFERENCES:
Tilford et al., J. Am. Chem. Soc. vol. 70, pp. 4001-4009 (1948).
Sperber et al., J. Am. Chem. Soc. vol. 71, pp. 887-890 (1948).
McCarty et al., J. Am. Chem. Soc. vol. 79, pp. 472-480 (1957).
Zelinski et al., J. Am. Chem. Soc. vol. 73, pp. 696-697 (1951).
Klein, Ber. Deut. Chem. vol. 23, pp. 2693-2696 (1890).
Abramovitch, Pyridine and Its Derivatives, vol. 14 Supplement Part 2, pp. 498-499 and 506-508, John Wiley and Sons, NY (1974).
Klingsberg, Pyridine and Its Derivatives, Part 4, pp. 27, 31, 33-41, Interscience Publishers, NY (1964).

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