2-Exo-hydroxy-endo-tricyclo[6.2.1.0.sup.2,7 ]undecane

Details 2-Exo-hydroxy-endo-tricyclo[6.2.1.0.sup.2,7 ]undecane 2-Exo-hydroxy-endo-tricyclo[6.2.1.0.sup.2,7 ]undecane

1984-07-03

1985-08-06

Lone, Werren B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

C07C 3522

Patent

active

045337705

ABSTRACT:
Disclosed is 2-exo-hydroxy-endo-tricyclo[6.2.1.0.sup.2,7 ]undecane represented by the following formula (I): ##STR1## The tricycloundecanol of the formula (I) has green, camphor-like and woody odor and is useful as an aroma chemical. Furthermore, owing to the aliphatic polycyclic structure like adamantyl alcohol, it is expected to have antiviral, antimicroviral and plant hormone activities.
The tricycloundecanol (I) of the invention is prepared by subjecting endo-tricyclo[6.2.1.0.sup.2,7 ]undecane to hydroxylation at the bridgehead position with a substituted perbenzoic acid.

REFERENCES:
patent: 4036892 (1977-07-01), Inamoto et al.
patent: 4036893 (1977-07-01), Inamoto et al.
patent: 4087467 (1978-05-01), Inamoto et al.
Swithenbank et al., "J. Chem. Soc." p. 4573 (1963).
Takaishi et al., "Synthesis" (1983), p. 293.

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