2-deoxyuridines and riboside precursors

Details 2-deoxyuridines and riboside precursors 2-deoxyuridines and riboside precursors

1985-09-19

1990-02-06

Griffin, Ronald W.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carbohydrates or derivatives

536 41, 536 23, C07H 19073, C07H 1100, C07H 2300

Patent

active

048989363

ABSTRACT:
A process is provided for the preparation of certain 2-deoxyuridines including the steps forming a substituted alkyl 5-O-"protected"-2-deoxyribofuranoside, hydrocarbylating the latter compound, and condensing the hydrocarbylated compound in the presence of a Lewis or Bronsted acid with a silyluracil to form a uridine. Several tritylated ribofuranosides are novel compounds per se.

REFERENCES:
Ikehara et al., Advances in Carbohydrate Chemistry and Biochemistry, vol. 36, pp. 135-213, 1979.
Wierenga et al., Carbohydrate Research, vol. 90, pp. 41-52, 1981.

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