(2-cyclopentenyl)chlorosilanes and their preparation methods

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

Reexamination Certificate

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C556S481000

Reexamination Certificate

active

07314946

ABSTRACT:
The present invention relates to (2-cyclopentenyl)chlorosilane derivatives and the preparation method thereof. In particular, it relates to a very economical process which reacts cyclopentadiene, which is formed by a cracking of industrially produced low-priced dicyclopentadiene, with a silane compound containing silicon-hydrogen bonds at elevated temperature in a hydrocarbon compound with a boiling point of a predetermined range, thus also enabling to prevent problematic production of dicyclopentadiene polymer by using the hydrocarbon compound. Further, in the presence of a group 10 metal compound catalyst, the process herein is capable of lowering the reaction temperature and increasing the yield in the reaction of sterically hindered alkyl-dichlorosilane. The (2-cyclopentenyl)chlorosilane may be useful in preparing an organic silicon compound containing an unsaturated group or a functional silicone polymer using the same, or in modifying the surface or manufacturing a thin layer.

REFERENCES:
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patent: 2002-226407 (2002-08-01), None
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Hayashi, Tamio; Kabeta, Keiji; Yamamoto, Tsunehiro; Tamao, Kohei; Kumada, Makoto: “Optically Active Cyclic Allylsilanese Preparation by Asymmetric Hydrosilylation and Anti Stereochemistry in SE1Reactions”,Tetrahedron Letters,vol. 24, No. 50 (1983) pp. 5661-5664.
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