2-Alkoxyacrylate process

Details 2-Alkoxyacrylate process 2-Alkoxyacrylate process

1980-04-18

1981-12-08

Trousof, Natalie

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

C07C 67327

Patent

active

043049281

ABSTRACT:
This invention relates to a process for producing 2-alkoxyacrylate by heating an alkyl 2,2-dialkoxypropionate with a molar amount each of a heterocyclic amine and an organic carboxylic acid halide in the presence of a catalytic amount of an inorganic base.

REFERENCES:
patent: 2440092 (1948-04-01), Hyman et al.
patent: 2571212 (1951-10-01), Croxall et al.
Claisen, L. Berichte, vol. 31 (1898) pp. 1019-1021.
Bordwell, F. et al. J. Am. Chem. Society, vol. 97, (1975) pp. 7006-7014.
Pearson, Ralph G. et al. J. Am. Chem. Society vol. 75 (1953) pp. 2439-2443.
House, H. O. "Modern Synthetic Reactions" (1965) Benjamin Press, Publ. p. 164.
Cram, Donald J. "Fundamentals of Carbanion Chemistry" (1965) Academic Press, Publ. p. 19.

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