2-Alkoxy-tetrahydrofurans via hydroformylation of allylic alcoho

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260615AA, 568867, 568865, C07D30720

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active

041234448

ABSTRACT:
2-Alkoxytetrahydrofurans are prepared by hydroformylation of an allylic alcohol in the presence of an alkanol and a rhodium hydroformylation catalyst. The products are useful, inter alia, as intermediates in the preparation of butanediols and substituted derivatives thereof.

REFERENCES:
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Adkins et al., Journal of the American Chemical society, vol. 70 (1948) pp. 383-386 and vol. 71 (1949) pp. 3051-3055.
Lawesson et al., Acta. Chem. Scand., vol. 14 (1960) pp. 1854 & 1855.
Brown et al., Tetrahedron Letters, vol. 22 (1969) pp. 1725 & 1726.
Brown et al., Journal of the Chemical Society (A) 1970, pp. 2753-2764.

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