2,6,6-Trimethyl-.alpha.-(iso)propenyl-1-cyclohexene-1-methanols

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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131 17R, 25217411, 252522R, 426534, 560187, 568826, C07C 3314

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active

042438233

ABSTRACT:
Processes and compositions are described for use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma, smoking tobacco flavor and aroma and perfume and perfumed article aroma augmenting, enhancing and imparting compositions; and as foodstuff, chewing gum, toothpaste, medicinal product, smoking tobacco, perfume and perfumed article aroma and/or flavor imparting materials of 2,6,6-trimethyl-.alpha.-(iso)propenyl-1-cyclohexene-1-methanol and -1,3-cyclohexadiene-1-methanol derivatives or one or more of their geometric or stereoisomers as defined by the generic structure: ##STR1## wherein one of R.sub.1, R.sub.2 or R.sub.3 is methyl and the other two of R.sub.1, R.sub.2 and R.sub.3 represents hydrogen; the dashed line is a carbon-carbon double bond or a carbon-carbon single bond; with the proviso that when R.sub.1 is hydrogen, the dashed line is a carbon-carbon double bond.
Addition of one or more of the 2,6,6-trimethyl-.alpha.-(iso)propenyl-1-cyclohexene-1-methanols or -1,3-cyclohexadiene-1-methanols of our invention to consumable materials is indicated to produce:

REFERENCES:
patent: 3928456 (1975-12-01), Kovats
patent: 3996296 (1976-12-01), Mookherjee
Rautenstrauch, Helv. Chim. Acta 56 2493 (1973).

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