2-5,disubstituted-7,7,8,8-tetracyanoquinodimethanes

Organic compounds -- part of the class 532-570 series – Organic compounds – Cyclohexadiene having atoms double bonded directly at the 1-...

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252500, 558430, 560126, 562508, 564152, C07C25531

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049507745

ABSTRACT:
A 2,5-disubstituted-7,7,8,8-tetracyanoquinodimethane of the general formula ##STR1## wherein R.sup.1 is hydrogen or methyl, X is COOR.sup.2 (in which R.sup.2 is hydrogen or C.sub.1-10 alkyl), --CONR.sup.3 R.sup.4 (in which R.sup.3 and R.sup.4 each is hydrogen or C.sub.1-4 alkyl) or --CN, provided that when R.sup.1 is hydrogen, X is --CN or --CONR.sup.3 R.sup.4. The tetracyanoquinodimethane derivatives are starting materials for the production of polyamides, polyurethanes or organic semiconductor devices.

REFERENCES:
patent: 3115506 (1963-12-01), Acker et al.
patent: 4772432 (1988-09-01), Miyashita
J. Am. Chem. Soc., 84, 3370 (1962)-"Substituted Quinodimethans, I, Preparation and Chemistry of 7,7,8,8-Tetracyanoquinodimethan".
J. Am. Chem. Soc. 84, 3374 (1962)-"Substituted Quinodimethans, II, Anion-Radical Derivatives and Complexes of 7,7,8,8-Tetracyanoquinodimethan."

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