Chemistry of carbon compounds – Miscellaneous organic carbon compounds
Patent
1976-03-19
1978-01-17
Czaja, Donald E.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
260 458NT, 260 4595D, 260953, C08K 536, C08K 553
Patent
active
040692000
ABSTRACT:
The compounds are trialkylsubstituted hydroxybenzylphosphonates and phosphinates having the formula ##STR1## WHEREIN R, R.sup.1 and R.sup.2 are independently lower alkyl or cycloalkyl groups, R.sup.3 is alkyl, alkyl substituted with one halogen atom, phenyl, phenyl substituted with alkyl groups, alkoxy, alkoxy substituted with one halogen group, phenoxy, phenoxy substituted with alkyl groups, alkylthioethoxy, alkylpolyoxyalkylenoxy, R.sup.4 is alkyl, alkylsubstituted with one halogen atom, cycloalkyl, phenyl, phenyl substituted with alkyl groups alkylthioethyl, thiobis-alkylene, alkyleneoxyalkylene, polyoxyalkylene, alkylpolyoxyalkylene, alkylene, polyvalent cyclic or acyclic hydrocarbon radical, R.sup.5 and R.sup.6 are independently hydrogen, alkyl of 1 to 12 carbon atoms, R.sup.6 may also be the group Ic ##STR2## OR TOGETHER R.sup.5 and R.sup.6 represent the group Id ##STR3## R.sup.7 is hydrogen, alkyl or phenyl, A is lower alkylene and n is 1 to 4. These compounds are usually prepared by reacting the trialkylsubstituted hydroxybenzyl or hydroxyphenylalkyl halide with the appropriate trialkyl or triaryl phosphite or appropriate substituted phosphonite.
The compounds are useful as stabilizers of organic materials subject to oxidative, thermal and photochemical degradation.
REFERENCES:
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patent: 3376258 (1968-04-01), Gysling et al.
patent: 3502613 (1970-03-01), Berger
patent: 3644279 (1972-02-01), Mathis et al.
patent: 3655614 (1972-04-01), Spivack
patent: 3767735 (1973-10-01), Fenyes et al.
patent: 3951912 (1976-04-01), Susi
patent: 3962376 (1976-06-01), Spivack et al.
Ciba-Geigy Corporation
Czaja Donald E.
Hall Luther A. R.
White R. A.
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