2,2-Dialkyltetrahydropyrans

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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252522R, C07D30904

Patent

active

042128129

ABSTRACT:
By treating a primary or secondary alkenol having an olefinic bond in the sixth position relative to the carbon atom carrying the hydroxyl group and at least one methyl group in the fifth position relative to said carbon atom with a strong acid (e.g., 85 percent phosphoric acid), 2,2-dialkyltetrahydropyrans are produced via a cyclization reaction. The products have desirable fragrance characteristics.

REFERENCES:
patent: 3163658 (1964-12-01), Eschinasi et al.
patent: 3166575 (1965-01-01), Naves et al.
patent: 3166576 (1965-01-01), Markus
patent: 3328426 (1967-06-01), Ohloff
patent: 3394169 (1968-07-01), Davis
patent: 3455997 (1969-07-01), Eschinasi
patent: 3649676 (1972-03-01), Galfre et al.

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