2,2'-Azobis(2,4-dimethylvaleronitrile) isomer mixture predominan

Organic compounds -- part of the class 532-570 series – Organic compounds – Azo

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252350, 526218, 5262181, 526260, 526263, 526291, 526317, 526328, 526330, 526341, 526343, 526344, 526338, 526352, 534573, 534887, C07C10700, C07C10702, C07C10704

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048269590

ABSTRACT:
A mixture of an isomer of 2,2'-azobis(2,4-dimethylvaleronitrile) having a low melting point in an amount of about 70% by weight or more and an isomer of 2,2'-azobis(2,4-dimethylvaleronitrile) having a high melting point in an amount of about 30% by weight or less shows excellent solvent solubility, which is higher than that of the isomer having a low melting point. The mixture is useful as a polymerization initiator, and also as a blowing agent.

REFERENCES:
patent: 2469358 (1949-05-01), Alderson et al.
patent: 2492763 (1949-12-01), Pinkney
patent: 3959343 (1976-05-01), Arashi et al.
patent: 3987025 (1976-10-01), Moore
patent: 4272435 (1981-06-01), Matsuda et al.
patent: 4315856 (1982-02-01), Moore
Lewis et al., J. Amer. Chem. Soc., vol. 71, pages 747 and 748 (1949).
Overberger et al. I, J. Amer. Chem. Soc., vol. 73, pages 2618 to 2621 (1951).
Overberger et al. II, J. Amer. Chem. Soc., vol. 71, pages 2661 to 2666 (1949).

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