Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1977-06-29
1979-01-16
Schwartz, Gerald A.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
26039745, 260586F, C07C 4948
Patent
active
041349202
ABSTRACT:
14.beta.-Hydroxyandrostanes and processes for the preparation thereof in which the 14.beta.-hydroxy group is fabricated internally by means of a novel cyclization of 8,14-seco-4,6,9(11)-androstatrien-3,14,17-triones is disclosed.
The 14.beta.-hydroxyandrostanes are useful as precursors for the synthesis of cardenolides and related products.
REFERENCES:
ruppert et al., Chem. Ber., vol. 106, pp. 3636-3644 (1973).
Gould George M.
Saxe Jon S.
Schwartz Gerald A.
Wittekind Raymond R.
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