14.beta.-Hydroxyandrostanes

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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26039745, 260586F, C07C 4948

Patent

active

041349202

ABSTRACT:
14.beta.-Hydroxyandrostanes and processes for the preparation thereof in which the 14.beta.-hydroxy group is fabricated internally by means of a novel cyclization of 8,14-seco-4,6,9(11)-androstatrien-3,14,17-triones is disclosed.
The 14.beta.-hydroxyandrostanes are useful as precursors for the synthesis of cardenolides and related products.

REFERENCES:
ruppert et al., Chem. Ber., vol. 106, pp. 3636-3644 (1973).

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