11-substituted-16-phenoxy and 16-substituted phenoxy-prostatrien

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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562463, C07C17700

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active

050576216

ABSTRACT:
This invention covers a compound of the formula ##STR1## wherein R is hydrogen, lower alkyl or a pharmaceutically acceptable, non-toxic salt of a compound wherein R is hydrogen; X is hydrogen, halo, trifluoromethyl, lower alkyl or lower alkoxy, Y is lower alkyl or ##STR2## wherein Z is hydrogen, halo, methyl, methoxy or trifluoromethyl; and the wavy lines represent the .alpha. or .beta. configuration with the proviso that when one wavy line is .alpha. the other is .beta..

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patent: 4187381 (1980-02-01), Holland et al.
patent: 4204074 (1980-05-01), Holland et al.
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"Prostaglandins and Cogeners IV, The Synthesis of Certain 11-Substituted Derivatives of 11-Deoxyprostaglandin E.sub.2 and F.sub.2.alpha. from 15-o-Acetylprostaglandin A.sub.2 Methy Ester", Grudzinskas et al., Tetrahedron Letters, No. 2, 141-144, 1973.
"Synthesis of Methylated Prostaglandins", Guzman et al., Chemistry and Industry, Jul. 7, 1973, 635-636.
"Voies Nouvelles en Synthese de Prostaglandines", Crabbe et al., Bull. Soc. Chim. Belg., vol. 86, No. 1-2, 109-124, 1977.
"The Total Synthesis of Prostaglandins by the Tropolone Route", Greene et al., J. Org. Chem., vol. 47, 2553, 1982.

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