((1-piperazinyl)carbonyl)phosphoramidothioate ester insecticides

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Phosphorus containing other than solely as part of an...

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544232, 558178, A01N 5732, C07F 96509

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active

049506579

ABSTRACT:
O,S-Dialkyl ((piperazinyl)carbonyl)phosphoramidothioates are prepared by the reaction of O,S-dialkyl phosphoroisocyanatidothioates with substituted piperazines and found to be effective plant systemic and contact insecticides. ((4-(1,1-Dimethylethyl)-1-piperazinyl)carbonyl)phosphoramidothioate, for example, is prepared from O,S-dimethyl phosphoroisocyanatidothioate and 4-(1,1-dimethylethyl)piperazine and found to control aster leafhoppers when applied to rice plants.

REFERENCES:
patent: 4225595 (1980-09-01), Fancher
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Samarai et al., Zh. Obshch. Khim., 39, 1480-1482 (1969) (English translation).
Derkach et al., Zh. Obshch. Khmi., 34, 3096-3098 (1964) (English translation).
Mel'nikov et al., (Chemical Abstracts, 87, 183905n (1977)).
Kristiansen et al., Chemical Abstracts, vol. 89, No. 179559 (1978), (Abstract for DE 2805682, 8/17/78).
Kristiansen et al., Chemical Abstracts, vol. 88, No. 70501 (1978), (Abstract for DE 2718554, 11/10/77).

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