1-Olefin polymer wax, and a process for the preparation thereof

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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585 9, 585522, 585523, 585524, C10L 116, C07C 224, C07C 202

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049622625

ABSTRACT:
1-Olefin polymer waxes having a very narrow molecular weight distribution, high isotacticity, a narrow grain size distribution and a high bulk density are obtained by means of a catalyst comprising a chiral, stereorigid metallocene compound and an aluminoxane, in the presence of small amounts of hydrogen during the polymerization.

REFERENCES:
patent: 4522982 (1985-06-01), Ewen
patent: 4542199 (1985-09-01), Kaminsky et al.
patent: 4704491 (1987-11-01), Tsutsui et al.
patent: 4769510 (1988-09-01), Kaminsky et al.
T. Tsutsui, "Production of Ethylene Wax", Mar. 14, 1987, vol. 11, No. 85 (C410) (2532) (Abstract of JP-A 61/236804 of Oct. 22, 1986.).
W. Kaminsky, "Stereoselektive Polymerization von Olefinen mit Homogenen, Chiralen Ziegler-Natta-Katalysatoren", Angew. Makromol. Chem., 145/146, 149-160 (1986).

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