1',6,6'-trimethacryloyl-2,3,3',4,4'-penta-O-methylsucrose

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbohydrates or derivatives

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536 185, 536120, 536 41, C07H 1500

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active

051169614

ABSTRACT:
A 1',6,6'-trimethylacryloyl-2,3,3',4,4'-penta-O-methylsucrose compound is disclosed. This compound is prepared by treating 2,3,3',4,4'-penta-O-methylsucrose with methacryloyl chloride in the presence of triethylamine and tetrahydrofuran. This compound is used as a crosslinking agent in the preparation of polymers.

REFERENCES:
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patent: 4151304 (1979-04-01), Evans
"Pacific Polymer Preprints", vol. 1, (Nov. 1989) pp. 113-114, Dinikov.
Dirilikov, "Monomers and Polymers based on Mono- and Dissaccharides", Pacific Polymer Preprints, vol. 1 (Dec. 12-15, 1989), pp. 113-114.
Hough et al., "Sucrochemistry, Part II,. 6,6'-Di-O-tritylsucrose", Carbohyd. Res., vol. 21 (1972), pp. 144-147.
Matsumoto et al., "Gelatin in the Copolymerization of Methyl Methacrylate with Trimethyolpropane Trimethacrylate", Eur. Polym. J., vol. 25, No. 4 (1989) pp. 385-389.
O'Donnell et al., "Synthesis of Some Partially Methylated Sucrose Derivatives", Aust. J. Chem., vol. 25 (1972), pp. 407-412.
Ogata et al., "Molecular Weight Control in Polycondensation of Hydroxyl Diesters with Hexamethylenediamine by Polymer Matrices", Journal of Polymer Science: Polymer Chemistry Edition, vol. 19 (1981), pp. 2609-2617.

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