Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing
Patent
1985-04-26
1988-11-15
Shaver, Paul F.
Organic compounds -- part of the class 532-570 series
Organic compounds
Silicon containing
556 81, 556 88, 556 89, 556437, 556444, 556446, 556470, 556482, 549214, C07F 708, C07F 710, C07F 718, C07F 722
Patent
active
047851260
ABSTRACT:
This invention resides in a process for production of predominantly a 1,4-O-metallation product of a hydride of silicon, germanium, or tin with an .alpha.,.beta.-unsaturated carbonyl compound. The reaction involved takes place in the presence of a heterogeneous noncomplexed rhodium-containing catalyst. This invention also resides in 1,4-O-metallation compositions having perfluoroalkyl R groups on either side of the C.dbd.C bond of an enol ether or on the acetal side of the C.dbd.C bond of a ketene acetal.
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E. I. Du Pont de Nemours and Company
Evans Craig H.
Shaver Paul F.
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